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See this [http://groups.google.com/group/c4lj-articles/browse_thread/thread/ba2efed674d66d7a post] for username and password information.
To use the XML file to do data entry, make sure the WordPress databases is up-to-date, go to http://journal.code4lib.org/issues/issue#/feed/doaj to get the necessary XML, edit the XML so each author is in a element by themselves, validate the XML against the Directory's schema, go to http://www.doaj.org/restricted and upload the friuts of your labors. For example, the XML for issue 5 is available at http://journal.code4lib.org/issues/issue5/feed/doaj.
This seems to supply some information about the feed and how to customize the XML for import into DOAJ, but doesn't actually provide XML: http://journal.code4lib.org/doaj/